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Identification |
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YMDB ID | YMDB00031 |
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Name | 7-phospho-2-dehydro-3-deoxy-D-arabino-heptonic acid |
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Species | Saccharomyces cerevisiae |
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Strain | Baker's yeast |
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Description | 7-phospho-2-dehydro-3-deoxy-D-arabino-heptonic acid, also known as 2-dahp or 3-deoxy-arabino-heptulonate 7-phosphate, belongs to the class of organic compounds known as monosaccharide phosphates. These are monosaccharides comprising a phosphated group linked to the carbohydrate unit. Based on a literature review very few articles have been published on 7-phospho-2-dehydro-3-deoxy-D-arabino-heptonic acid. |
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Structure | |
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Synonyms | - 2-Dahp
- 2-Dehydro-3-deoxy-D-arabino-heptonate 7-phosphate
- 2-dehydro-3-Deoxy-D-arabino-heptonic acid 7-phosphoric acid
- 2-dehydro-3-Deoxy-D-arabino-heptulosonic acid-7-phosphate
- 3-Deoxy-arabino-heptulonate 7-phosphate
- 3-Deoxy-arabino-heptulonic acid 7-phosphoric acid
- 3-Deoxy-D-arabino-2-heptulosonate 7-(dihydrogen phosphate)
- 3-Deoxy-D-arabino-2-heptulosonic acid
- 3-deoxy-D-arabino-2-heptulosonic acid 7-(dihydrogen phosphate)
- 3-Deoxy-D-arabino-2-heptulosonic acid 7-(dihydrogen phosphoric acid)
- 3-Deoxy-D-arabino-hept-2-ulosonate 7-phosphate
- 3-Deoxy-D-arabino-hept-2-ulosonic acid 7-phosphoric acid
- 3-Deoxy-D-arabino-heptulosonate 7-phosphate
- 3-deoxy-D-arabino-heptulosonate-7-phosphate
- 3-Deoxy-D-arabino-heptulosonic acid 7-phosphate
- 3-Deoxy-D-arabino-heptulosonic acid 7-phosphoric acid
- 3-Deoxy-D-arabino-heptulosonic acid-7-phosphoric acid
- 3-Deoxyarabinoheptulosonate-7-phosphate
- 7-phospho-2-keto-3-Deoxy-D-arabinoheptonate
- DAHP
- 7-Phospho-2-dehydro-3-deoxy-D-arabino-heptonate
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CAS number | 2627-73-8 |
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Weight | Average: 288.1459 Monoisotopic: 288.024633148 |
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InChI Key | PJWIPEXIFFQAQZ-PUFIMZNGSA-N |
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InChI | InChI=1S/C7H13O10P/c8-3(1-4(9)7(12)13)6(11)5(10)2-17-18(14,15)16/h3,5-6,8,10-11H,1-2H2,(H,12,13)(H2,14,15,16)/t3-,5-,6+/m1/s1 |
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IUPAC Name | (4R,5S,6R)-4,5,6-trihydroxy-2-oxo-7-(phosphonooxy)heptanoic acid |
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Traditional IUPAC Name | DAHP |
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Chemical Formula | C7H13O10P |
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SMILES | O[C@H](COP(O)(O)=O)[C@@H](O)[C@H](O)CC(=O)C(O)=O |
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Chemical Taxonomy |
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Description | belongs to the class of organic compounds known as monosaccharide phosphates. These are monosaccharides comprising a phosphated group linked to the carbohydrate unit. |
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Kingdom | Organic compounds |
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Super Class | Organic oxygen compounds |
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Class | Organooxygen compounds |
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Sub Class | Carbohydrates and carbohydrate conjugates |
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Direct Parent | Monosaccharide phosphates |
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Alternative Parents | |
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Substituents | - Heptose monosaccharide
- Monosaccharide phosphate
- Medium-chain keto acid
- Monoalkyl phosphate
- Sugar acid
- Alpha-keto acid
- Alkyl phosphate
- Beta-hydroxy ketone
- Phosphoric acid ester
- Organic phosphoric acid derivative
- Keto acid
- Alpha-hydroxy ketone
- Secondary alcohol
- Ketone
- Polyol
- Carboxylic acid derivative
- Carboxylic acid
- Monocarboxylic acid or derivatives
- Alcohol
- Carbonyl group
- Organic oxide
- Hydrocarbon derivative
- Aliphatic acyclic compound
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Molecular Framework | Aliphatic acyclic compounds |
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External Descriptors | |
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Physical Properties |
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State | Not Available |
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Charge | 0 |
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Melting point | Not Available |
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Experimental Properties | Property | Value | Reference |
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Water Solubility | Not Available | PhysProp | LogP | Not Available | PhysProp |
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Predicted Properties | |
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Biological Properties |
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Cellular Locations | |
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Organoleptic Properties | Not Available |
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SMPDB Pathways | Not Available |
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KEGG Pathways | Phenylalanine, tyrosine and tryptophan biosynthesis | ec00400 | |
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SMPDB Reactions | Not Available |
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KEGG Reactions | |
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Concentrations |
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Intracellular Concentrations | Not Available |
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Extracellular Concentrations | Not Available |
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Spectra |
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Spectra | Spectrum Type | Description | Splash Key | View |
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Predicted GC-MS | Predicted GC-MS Spectrum - GC-MS (Non-derivatized) - 70eV, Positive | splash10-006w-6920000000-01ac7cd5df7cb6d11ab7 | JSpectraViewer | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - 10V, Positive | splash10-00du-1490000000-b500894b2362a345803f | JSpectraViewer | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - 20V, Positive | splash10-0006-5930000000-a9d3893a2dec466630ee | JSpectraViewer | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - 40V, Positive | splash10-00xr-9700000000-3199033968d25ee1d235 | JSpectraViewer | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - 10V, Negative | splash10-002k-6940000000-98d2442ffe3031d309f1 | JSpectraViewer | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - 20V, Negative | splash10-004i-9200000000-37861b420da4e96055ac | JSpectraViewer | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - 40V, Negative | splash10-004i-9000000000-0ba308fea596aa1da1c2 | JSpectraViewer | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - 10V, Positive | splash10-007c-1590000000-5032f9123dae327ae7fd | JSpectraViewer | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - 20V, Positive | splash10-0fr2-9700000000-7ee2c3c29df5d7c3c466 | JSpectraViewer | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - 40V, Positive | splash10-0002-9100000000-5648242eb0703edfc1a4 | JSpectraViewer | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - 10V, Negative | splash10-00kr-2090000000-303f8ce9daad2d0d8370 | JSpectraViewer | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - 20V, Negative | splash10-0002-9300000000-b3e39bf1c93cf778ae7c | JSpectraViewer | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - 40V, Negative | splash10-004j-9000000000-5c6f9eb036b780095d5a | JSpectraViewer | 1D NMR | 13C NMR Spectrum | Not Available | JSpectraViewer | 1D NMR | 1H NMR Spectrum | Not Available | JSpectraViewer | 1D NMR | 13C NMR Spectrum | Not Available | JSpectraViewer | 1D NMR | 1H NMR Spectrum | Not Available | JSpectraViewer | 1D NMR | 13C NMR Spectrum | Not Available | JSpectraViewer | 1D NMR | 1H NMR Spectrum | Not Available | JSpectraViewer | 1D NMR | 13C NMR Spectrum | Not Available | JSpectraViewer | 1D NMR | 1H NMR Spectrum | Not Available | JSpectraViewer | 1D NMR | 13C NMR Spectrum | Not Available | JSpectraViewer | 1D NMR | 1H NMR Spectrum | Not Available | JSpectraViewer | 1D NMR | 13C NMR Spectrum | Not Available | JSpectraViewer | 1D NMR | 1H NMR Spectrum | Not Available | JSpectraViewer | 1D NMR | 13C NMR Spectrum | Not Available | JSpectraViewer | 1D NMR | 1H NMR Spectrum | Not Available | JSpectraViewer | 1D NMR | 13C NMR Spectrum | Not Available | JSpectraViewer | 1D NMR | 1H NMR Spectrum | Not Available | JSpectraViewer | 1D NMR | 13C NMR Spectrum | Not Available | JSpectraViewer | 1D NMR | 1H NMR Spectrum | Not Available | JSpectraViewer | 1D NMR | 13C NMR Spectrum | Not Available | JSpectraViewer | 1D NMR | 1H NMR Spectrum | Not Available | JSpectraViewer |
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References |
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References: | - UniProt Consortium (2011). "Ongoing and future developments at the Universal Protein Resource." Nucleic Acids Res 39:D214-D219.21051339
- Herrgard, M. J., Swainston, N., Dobson, P., Dunn, W. B., Arga, K. Y., Arvas, M., Bluthgen, N., Borger, S., Costenoble, R., Heinemann, M., Hucka, M., Le Novere, N., Li, P., Liebermeister, W., Mo, M. L., Oliveira, A. P., Petranovic, D., Pettifer, S., Simeonidis, E., Smallbone, K., Spasic, I., Weichart, D., Brent, R., Broomhead, D. S., Westerhoff, H. V., Kirdar, B., Penttila, M., Klipp, E., Palsson, B. O., Sauer, U., Oliver, S. G., Mendes, P., Nielsen, J., Kell, D. B. (2008). "A consensus yeast metabolic network reconstruction obtained from a community approach to systems biology." Nat Biotechnol 26:1155-1160.18846089
- Konig, V., Pfeil, A., Braus, G. H., Schneider, T. R. (2004). "Substrate and metal complexes of 3-deoxy-D-arabino-heptulosonate-7-phosphate synthase from Saccharomyces cerevisiae provide new insights into the catalytic mechanism." J Mol Biol 337:675-690.15019786
- Larimer, F. W., Morse, C. C., Beck, A. K., Cole, K. W., Gaertner, F. H. (1983). "Isolation of the ARO1 cluster gene of Saccharomyces cerevisiae." Mol Cell Biol 3:1609-1614.6355828
- Teshiba, S., Furter, R., Niederberger, P., Braus, G., Paravicini, G., Hutter, R. (1986). "Cloning of the ARO3 gene of Saccharomyces cerevisiae and its regulation." Mol Gen Genet 205:353-357.2880280
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Synthesis Reference: | Not Available |
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External Links: | |
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