{"ymdb_id":"YMDB02300","created_at":"2012-06-08T16:16:32.000Z","updated_at":"2016-09-08T18:37:48.000Z","name":"Glucosan","cas":"498-07-7","state":"Solid","melting_point":"183 oC","description":"Glucosan is a monosaccharide anhydride compound present in biomass combustion smoke, and is a tracer for biomass burning sources in atmospheric aerosol particles. A product of cellulose combustion; when cellulose is heated to over 300 degree centigrade, it undergoes various pyrolytic processes, yielding a highly combustible tar, a major constituent of which is glucosan, a dehydrated glucose containing a ketal functional group.","experimental_water_solubility":"62.3 mg/mL [HMP experimental]","experimental_logp_hydrophobicity":null,"location":null,"synthesis_reference":"Tanaka, Choji.  Anhydrosugars. I. Constitutions of anhydrosugars.    Memoirs of the College of Science, University of Kyoto, Series A  (1930),  13  239-53.","chebi_id":"30997","hmdb_id":"HMDB00640","kegg_id":null,"pubchem_id":"2724705","cs_id":null,"foodb_id":null,"wikipedia_link":null,"biocyc_id":null,"iupac":"(1R,2S,3S,4R,5R)-6,8-dioxabicyclo[3.2.1]octane-2,3,4-triol","traditional_iupac":"levoglucosan","logp":"-1.7708356456666667","pka":"13.215582381313808","alogps_solubility":"1.60e+03 g/l","alogps_logp":"-2.18","alogps_logs":"0.99","acceptor_count":"5","donor_count":"3","rotatable_bond_count":"0","polar_surface_area":"79.15","refractivity":"32.41329999999999","polarizability":"14.130250612602248","formal_charge":"0","physiological_charge":"0","pka_strongest_basic":"-3.6486679661074968","pka_strongest_acidic":"12.212605412524747","bioavailability":"1","number_of_rings":"2","rule_of_five":"1","ghose_filter":"0","veber_rule":"0","mddr_like_rule":"0","synonyms":[" 1,6-Anhydro-b-D-glucopyranose"," 1,6-Anhydro-b-D-glucose"," 1,6-Anhydro-beta-D-glucopyranose"," 1,6-Anhydro-beta-D-glucose"," 1,6-Anhydro-beta-delta-glucopyranose"," 1,6-Anhydro-beta-delta-glucose"," 1,6-Anhydro-beta-glucopyranose"," 1,6-Anhydro-delta-glucose"," 1,6-Anhydroglucose"," 6,8-Dioxabicyclo[3.2.1]octane b-D-glucopyranose deriv."," 6,8-Dioxabicyclo[3.2.1]octane b-delta-glucopyranose deriv."," Anhydro-d-mannosan"," Anhydro-delta-mannosan"," Leucoglucosan"," Levoglucosan","1,6-Anhydro-D-glucose"],"pathways":[],"growth_conditions":[],"references":[{"pubmed_id":17439666,"citation":"Castrillo, J. I., Zeef, L. A., Hoyle, D. C., Zhang, N., Hayes, A., Gardner, D. C., Cornell, M. J., Petty, J., Hakes, L., Wardleworth, L., Rash, B., Brown, M., Dunn, W. B., Broadhurst, D., O'Donoghue, K., Hester, S. S., Dunkley, T. P., Hart, S. R., Swainston, N., Li, P., Gaskell, S. J., Paton, N. W., Lilley, K. S., Kell, D. B., Oliver, S. G. (2007). \"Growth control of the eukaryote cell: a systems biology study in yeast.\" J Biol 6:4."}],"proteins":[]}